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Phthalimide계 신규 Azo dye의 Polyurethane계 섬유 염색 특성

Dyeing Properties of Polyurethane Fiber by Novel Phthalimidyl Azo Disperse Dye

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초록

Some phthalimidyl azo dyes containing N,N-diethyl or N,N-di(β-methoxycarbonylethyl) group have been attempted to apply onto two kinds of polyurethane based materials and rationalize their dyeability and fastness comparing with those of some commercial disperse dyes. Phthalimidyl azo dye showed 66~98% of exhaustion yield at 120℃ by a conventional exhaust dyeing method. The dyeings were found to have a higher wash fastness with both fabrics in comparison with those of commercial dyes which indicates lower thermomigration and efficient alkali clearable properties of phthalimidyl ring and/or diester group during post-dyeing process.

Abstract

Some phthalimidyl azo dyes containing N,N-diethyl or N,N-di(β-methoxycarbonylethyl) group have been attempted to apply onto two kinds of polyurethane based materials and rationalize their dyeability and fastness comparing with those of some commercial disperse dyes. Phthalimidyl azo dye showed 66~98% of exhaustion yield at 120℃ by a conventional exhaust dyeing method. The dyeings were found to have a higher wash fastness with both fabrics in comparison with those of commercial dyes which indicates lower thermomigration and efficient alkali clearable properties of phthalimidyl ring and/or diester group during post-dyeing process.

참고문헌 (10)

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  2. D. Brierley, "The use of disperse dyes containing diester groups to produce discharge effects on fully dyed lightweight polyester fabrics", J.S.D.C., 99, pp.358~363 (1983)
  3. J. Mokhtari, "Novel hydrolysable azo disperse dyes based on N-ester-1,8-naphthalimide: dyeing of polyester-cotton blends", Coloration Technology, 124(5), pp.295~300 (2008)
  4. J. S. Koh, "Synthesis and Spectral Properties of Phthalimide Based Alkali-clearable Azo Disperse Dyes", Fibers and Polymers, 9(2), pp.143~151 (2008)
  5. J. H. Choi, "High fastness heterocyclic azo disperse dyes bearing ester functions", J.S.D.C., 115(1), pp.32~37 (1999)
  6. 한국섬유공학회, "최신 합성섬유", pp.265~284 (2001), 형설출판사
  7. 박종호, "분산염료 분자구조에 따른 PU-함침 폴리에스터의 염색성", 한국섬유공학회지, 45(3), pp.186~191 (2008), 한국섬유공학회
  8. J. H. Choi, "Novel azo disperse dye derived from phthalimide Part 1: Synthesis and spectroscopic properties", Coloration Technology, 124(2), pp.92~99 (2008)
  9. J. H. Choi, "Novel azo disperse dye derived from phthalimide containing ester groups", Coloration Technology
  10. J. H. Choi, "Novel azo disperse dye derived from phthalimide Part 2: Dyeing properties and colour fastness on polyester fibre", Coloration Technology, 124(6), pp.364~369 (2008)

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