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경유 대체연료로서 수첨바이오디젤의 윤활 특성 연구

Lubricity Characterization of Hydrogenated Biodiesel as an Alternative Diesel Fuel

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주제분류기계공학

초록

Paraffin bio-based hydrotreated biodiesel(HBD) is originated from vegetable oil(the process can also be applied to animal fat) with the the chemical structure CnH2n+2. In the number of process of the oil or fat, the hydrogenation is significantly important to create a bio-based diesel fuel. This study is focused on lubricity characteristics of BTL diesel blends to use alternative diesel fuel in Korea. The BTL diesel are blended the different volume ratios (HBD 5(5 vol.% HBD - 95 vol.% diesel), HBD 10, HBD 20, HBD 30, HBD 40 and HBD 50. HBD with paraffin compounds showed a very high centane number, low sulfur content and free aromatic compound. Especially, the wear scar of HBD showed poor lubricity compared to automotive diesel due to the fuel composition, low sulfur content and free aromatic compound. Also, the lubricity specification of automotive diesel with different six HBD blends is within the limit by the Korean standards. Finally, HBD as an alternative diesel fuel is challengeable in transportation sector of Korea.

Abstract

Paraffin bio-based hydrotreated biodiesel(HBD) is originated from vegetable oil(the process can also be applied to animal fat) with the the chemical structure CnH2n+2. In the number of process of the oil or fat, the hydrogenation is significantly important to create a bio-based diesel fuel. This study is focused on lubricity characteristics of BTL diesel blends to use alternative diesel fuel in Korea. The BTL diesel are blended the different volume ratios (HBD 5(5 vol.% HBD - 95 vol.% diesel), HBD 10, HBD 20, HBD 30, HBD 40 and HBD 50. HBD with paraffin compounds showed a very high centane number, low sulfur content and free aromatic compound. Especially, the wear scar of HBD showed poor lubricity compared to automotive diesel due to the fuel composition, low sulfur content and free aromatic compound. Also, the lubricity specification of automotive diesel with different six HBD blends is within the limit by the Korean standards. Finally, HBD as an alternative diesel fuel is challengeable in transportation sector of Korea.

참고문헌 (8)

  1. 김재곤, "해외 주요국 수송용 바이오연료의 혼합의무 정책비교 분석 연구", 신재생에너지, 7(4), pp.18~29 (2011), 한국신·재생에너지학회
  2. 서영웅, "수첨바이오디젤 생산기술의 최근 동향 및전망", 공업화학전망, 11(33), pp.35~45 (2008)
  3. "Neste Oil, Neste Oil" (2012)[URL]
  4. Bezergianni, S., "Hydrotreating of Watste Cooking Oil for Biodiesel Production. Part II: Effect of Temperature on Hydrocarbon Composition", Bioresour. Technol, 101, pp.7658~7660 (2010)
  5. NExBTL-Biodiesl Fuel of the Sencond Generation, "Rantanen, L.", ~, pp.SAE Technical Paper 01-3771 (2005)
  6. Huber, G. W., "Processing Biomass in Conventional Oil Refineries: Production of High Quality Diesel by Hydrotreating Vegetable Oils in Heavy Vacuum Oil Mixtures", Applied Catalysis A : General, 329, pp.120~129 (2007)
  7. Daniel, P. G., "Effect of Specific Fatty Acid Esters on Diesel Fuel Lubricity", Fuel, 83, pp.2351~2356 (2004)
  8. Danping, W., "The Lubricity of Diesel Fuels", Wear, 111, pp.217~235 (1986)

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