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Direct Coloration using Self-assembly Fabrication Method on PET Fibers

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초록

The electrostatic layer-by-layer technique provides a convenient way to control the construction of ultrathin films at nano-scale ranges and can be easily obtained. It can be also applicable to fiber substrate with dye compounds. We have fabricated multilayer dye films using diazonium resin and three couplers, which are prepared by self-assembly approach. This method is based on layer-by-layer deposition using electrostatic attraction between oppositely charged ions. Beside, the diazo coupling reaction proceeded to form azo dye layer on the PET fibers the same time. The corresponding results of the multilayer films have been discussed on the level of color strength (K/S).

Abstract

The electrostatic layer-by-layer technique provides a convenient way to control the construction of ultrathin films at nano-scale ranges and can be easily obtained. It can be also applicable to fiber substrate with dye compounds. We have fabricated multilayer dye films using diazonium resin and three couplers, which are prepared by self-assembly approach. This method is based on layer-by-layer deposition using electrostatic attraction between oppositely charged ions. Beside, the diazo coupling reaction proceeded to form azo dye layer on the PET fibers the same time. The corresponding results of the multilayer films have been discussed on the level of color strength (K/S).

참고문헌 (10)

  1. "Polypeptide multilayer films on colloidal particles An in situ electro- optical study", 308, pp.309~317 (2007)
  2. "Covalently attached multilayer assemblies of diazo-resins and binuclear cobalt phthalocyanines", 478, pp.310~317 (2005)
  3. "Electrostatic layer-by-layer self-assembly of anionic squarylium and cationic polyelectrolyte", 69, pp.108~110 (2006)
  4. "Enzymatic desorption of layer-by-layer assembled multilayer films and effects on the release of encapsulated indomethacin microcrystals", 342, pp.2237~2243 (2007)
  5. "Preparation of dye thin films on fibers by electrostatic layer-by- layer adsorption", pp.149~150 (2006)
  6. "Enzymatic reduction and oxidation of fiber-bound azo- dyes", 40, pp.1732~1738 (2007)
  7. "The effects of reductant and carbon source on the microbial decolorization of azo dyes in an anaerobic sludge process", 76, pp.256~263 (2008)
  8. "Degradation of textile reactive Azo dye by a combined chemical-biological process: Fenton's reagent-yeast", 41, pp.1103~1109 (2007)
  9. "Self-assembly multi-layer of diazonium resin and its coupling reaction with J-acid and H-acid", 72, pp.345~348 (2007)
  10. "Self-assembly of homopolymer and copolymers of N-4-hydroxyphenyl-acrylamide with diazoresin via H-bonding attraction", 38, pp.2077~2082 (2002)

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