Photoinitiator-free Photo-reactive Coloration of Wool Fabrics Using C.I. Reactive Black 5
2
조회
0
다운로드
1
인용
0
참고문헌
키워드
초록
Abstract: Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/cm2. Furthermore, the photochemically dyed wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing.
Abstract
Abstract: Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/cm2. Furthermore, the photochemically dyed wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing.
참고문헌 (32)
- R. M. Christie, "The Chemistry of Colour Application", pp.98~108 (2000), Blakwell
- D. M. Lewis, "Wool Dyeing", pp.176~253 (1992), Society of Dyers and Colourists
- R. M. Christie, "Environmental Aspects of Textile Dyeing", pp.83~138 (2007), Textile Institute and Woodhead
- P. Suwanruji, "Studies toward a Universal Dye for Textile Fibres", Color. Technol., 120, pp.220~ (2004)
- D. M. Lewis, "Coloration in the Next Century", Rev. Prog. Coloration, 29, pp.23~ (1999)
- C. W. Kan, "The Effect of Low-temperature Plasma on the Chrome Dyeing of Wool Fibre", J. Materials Processing Technol., 82, pp.122~ (1998)
- C. W. Kan, "Surface Properties of Low-temperature Plasma Treated Wool Fabrics", J. Materials Processing Technol., 83, pp.180~ (1998)
- D. Fakin, "The Impact of Corona Modified Fibers’ Chemical Changes on Wool Dyeing", J. Materials Processing Technol., 209, pp.584~ (2009)
- M. N. Micheal, "Efficiency of Ultraviolet", Ozone Treatments in the Improvement of the Dyeability and Light Fastness of Wool, 2003, pp.90, 3668~
- R. Atav, "Effect of the Ozonation Process on the Dyeability of Mohair Fibres", Color. Technol., 127, pp.159~ (2011)
- A. Bhattacharya, "Grafting: A Versatile Means to Modify Polymers Techniques, Factors and Applications", Prog. Polym. Sci., 29, pp.767~ (2004)
- A. M. Naggar, "Dyeing, Moisture Regain and Mechanical Properties of Wool Fabric Grafted with PMMA by Chemical and Radiation-grafted Methods", Radiat. Phys. Chem., 47, pp.623~ (1996)
- Y. Y. Dong, "Union Dyeing of the Photografted PET", Wool Blend Fabrics with Dimethylaminopropyl Methacrylamide, 201004, pp.11, 213~217[DOI]
- E. Partouche, "Surface Modification of Crosslinked Poly(Styrene-divinyl benzene) Micrometer-sized Particles of Narrow Size Distribution by Ozonolysis", J. Colloid Interface Sci., 294, pp.69~ (2006)
- Z. Xu, "Effect of γ-ray Irradiation Grafting on the Carbon Fibers and Interfacial Adhesion of Epoxy Composites", Composites Sci. Technol., 67, pp.3261~ (2007)
- A. Vahdat, "Radiation Grafting of Styrene onto Polypropylene Fibres by a 10 MeV Electron Beam", Radiat. Phys. Chem., 76, pp.787~ (2007)
- M. Okubo, "Surface Modification of Fluorocarbon Polymer Film for Improved Adhesion using Atmospheric-pressure Nonthermal Plasma Graft-polymerization", Thin Solid Films, 516, pp.6592~ (2008)
- J. Lei, "Surface Graft Copolymerization of Hydrogen Silicone Fluid onto Fabric Through Corona Discharge and Water Repellency of Grafted Fabric", Eur. Polym. J., 36, pp.1277~ (2000)
- F. C. Loh, "Near-UV Radiation Induced Surface Graft Copolymerization of Some O3-pretreated Conventional Polymer Films", Eur. Polym. J., 31, pp.481~ (1995)
- 장진호, "자외선 경화형 인계 단량체를 이용한 면직물의 방염가공", 한국염색가공학회지, 20(4), pp.8~14 (2008), 한국염색가공학회
- K. H. Hong, "UV-induced Graft Polymerizaiton of Acrylamide on Cellulose by using Immobilized Benzophenone as Photo-initiator", Eur. Polym. J., 45, pp.1443~ (2009)
- A. M. Shanmugharaj, "Modificaiton of Rubber Surface by UV Surface Grafting", Appl. Surf. Sci., 252, pp.5714~ (2006)
- S. Hu, "Surface Modification of Poly (dimethylsiloxane) Microfluidic Devices by Ultraviolet Polymer Grafting", Anal. Chem., 74, pp.4117~ (2002)
- Yuanyuan Dong, "Novel Coloration of Cotton Fabrics by UV-induced Phtografting of Reactive Black 5 and Acrylic acid", 한국염색가공학회지, 23(1), pp.11~20 (2011), 한국염색가공학회
- J. Xue, "Degradation Mechanism of Alizarin Red in Hybrid Gas-Liquid Phase Dielectric Barrier Discharge Plasmas: Experimental and Theoretical Examination", Chem. Eng. J., 138, pp.120~ (2008)
- D. Meadows, "Vinyl Sulfones: Synthetic Preparations and Medicinal Chemistry Applications", Med. Res. Rev., 26, pp.793~ (2006)
- E. A. Bekturov, "Swelling of Poly(2-methyl-5-vinylpyridine) Gel in Linear Sodium Poly(vinylsulfonate) Solution", Macromol. Chem. Phys., 199, pp.1071~ (1998)
- H. S. Choe, "Preparation and Characterization of Poly (vinyl sulfone) and Poly(vinylidene fluoride)-Based Electrolytes", Electrochim. Acta, 40, pp.2289~ (1995)
- J. Chen, "Interaction of Diazoresins and Sulfonate Containing Polyelectrolytes", Polym. Int., 49, pp.382~ (2000)
- N. Inagaki, "Surface Modification of Poly(tetrafluoroethylene) Film by Plasma Graft Polymerization of Sodium Vinylsulfonate", J. Appl. Polym. Sci., 66, pp.77~ (1997)
- D. M. Lewis, "Colour and Textile Chemistry", pp.1~31 (2008), AATCC
- X. Bingshe, "The Structural Analysis of Biomacromolecule Wool Fiber with Ag-loading SiO2 Nanoantibacterial Agent by UV Radiation", J. Photochem. Photobiol. A: Chem., 188, pp.98~ (2007)