본문 바로가기
KERD
논문KCI 등재

육방정질화붕소 나노플레이크/폴리이미드 복합체를 이용한 마찰전기 나노발전기 평가

Evaluation of h-BN Nanoflakes/Polyimide Composites for a Triboelectric Nanogenerator

0

조회

0

다운로드

2

인용

0

참고문헌

키워드

주제분류기계공학

초록

A means of enhancing the performance of triboelectric nanogenerators (TENGs) is increasing the differences in work functions between contacting materials. Hexagonal boron nitride (h-BN) exhibits excellent mechanical properties and high chemical stability as well as a high work function. As a result, engineers in the field of energy harvesting have envisioned using h-BN in the electrification layer in TENGs. For the industrial application of h-BN in TENGs, large-scale production is necessary, and h-BN is generally exfoliated and dispersed in various solvents. In this study, we evaluate the performance of a TENG with h-BN nanoflakes in the polyimide (PI) layer. To synthesize a PI composite containing h-BN nanoflakes, h-BN powders are exfoliated and dispersed in poly(amic acid) (PAA), which is the precursor of PI. Then, h-BN dispersion is spin-coated onto the PI film and cured for 2 h under 300oC. This composite material can then be used for the electrification layer in TENGs. Below the electrification layer, an aluminum foil is placed and used as an electrode. When the contact and separation processes with polyethylene terephthalate are repeated, the fabricated TENG shows a maximum power density of 190.8 W/m2. This study shows that h-BN is a promising material for enhancing the performance of the electrification layer in TENGs.

Abstract

A means of enhancing the performance of triboelectric nanogenerators (TENGs) is increasing the differences in work functions between contacting materials. Hexagonal boron nitride (h-BN) exhibits excellent mechanical properties and high chemical stability as well as a high work function. As a result, engineers in the field of energy harvesting have envisioned using h-BN in the electrification layer in TENGs. For the industrial application of h-BN in TENGs, large-scale production is necessary, and h-BN is generally exfoliated and dispersed in various solvents. In this study, we evaluate the performance of a TENG with h-BN nanoflakes in the polyimide (PI) layer. To synthesize a PI composite containing h-BN nanoflakes, h-BN powders are exfoliated and dispersed in poly(amic acid) (PAA), which is the precursor of PI. Then, h-BN dispersion is spin-coated onto the PI film and cured for 2 h under 300oC. This composite material can then be used for the electrification layer in TENGs. Below the electrification layer, an aluminum foil is placed and used as an electrode. When the contact and separation processes with polyethylene terephthalate are repeated, the fabricated TENG shows a maximum power density of 190.8 W/m2. This study shows that h-BN is a promising material for enhancing the performance of the electrification layer in TENGs.

참고문헌 (11)

  1. Kim, S., "Transparent flexible graphene triboelectric nanogenerators", Advanced materials, 26(23), pp.3918~3925 (2014)
  2. Dong, Y., "Metallic MXenes : A new family of materials for flexible triboelectric nanogenerators", Nano Energy, 44, pp.103~110 (2018)
  3. Muralidharan, N., "Ultralow frequency electrochemicalmechanical strain energy harvester using 2D black phosphorus nanosheets", ACS Energy Letters, 2(8), pp.1797~1803 (2017)
  4. 박선영, "액체-고체 접촉대전을 위한 PET 기판 기반 ODA", PDMS딥 코팅 제조 및 평가, 2021, pp.37(2), 71~76[DOI]
  5. Bhimanapati, G. R., "Recent advances in two-dimensional materials beyond graphene", ACS nano, 9(12), pp.11509~11539 (2015)
  6. Butler, S. Z., "Progress, challenges, and opportunities in two-dimensional materials beyond graphene", ACS nano, 7(4), pp.2898~2926 (2013)
  7. Nayak, A. P., "Pressure-dependent optical and vibrational properties of monolayer molybdenum disulfide", Nano letters, 15(1), pp.346~353 (2015)
  8. Lee, C., "Measurement of the elastic properties and intrinsic strength of monolayer graphene", Science, 321(5887), pp.385~388 (2008)
  9. Lee, J. S., "Wafer-scale single-crystal hexagonal boron nitride film via self-collimated grain formation", Science, 362(6416), pp.817~821 (2018)
  10. Lee, G. -J., "Piezoelectric energy harvesting from two-dimensional boron nitride nanoflakes", ACS applied materials & interfaces, 11(41), pp.37920~37926 (2019)
  11. 조대현, "초순수 용매 내 육방정 질화붕소 나노시트의 농도와크기의 관계", 한국트라이볼로지학회지, 35(6), pp.343~349 (2019), 한국트라이볼로지학회[DOI]

관련 논문AI추천

이 간행물의 다른 논문 (4건)