Effect of biofibers addition on the structure and properties of soy protein composite films
2
조회
0
다운로드
0
인용
0
참고문헌
키워드
초록
Soy protein isolate (SPI) has garnered researchers' attention due to its abundance, costeffectiveness, excellent biocompatibility, hemo-compatibility, and biodegradability. However, SPI faces limitations in application due to poor processability and weak mechanical strength. Substantial efforts have been made to address these challenges. In this preliminary study, glycerol and biofibers were added to SPI to improve the mechanical properties and film forming, and glyoxal was employed to crosslink SPI molecules. The microstructure and mechanical properties of the resulting SPI/composite films were evaluated. A 15% addition of glycerol proved sufficient for good film formation. Among the biofibers, short SF microfibers were the most effective in enhancing breaking strength, while TEMPO-oxidized CNF (cellulose nanofiber) excelled among CNFs. Crosslinking with glyoxal significantly enhanced the mechanical properties, with the type of biofiber minimally affecting the mechanical properties of the crosslinked SPI composite films.
Abstract
Soy protein isolate (SPI) has garnered researchers' attention due to its abundance, costeffectiveness, excellent biocompatibility, hemo-compatibility, and biodegradability. However, SPI faces limitations in application due to poor processability and weak mechanical strength. Substantial efforts have been made to address these challenges. In this preliminary study, glycerol and biofibers were added to SPI to improve the mechanical properties and film forming, and glyoxal was employed to crosslink SPI molecules. The microstructure and mechanical properties of the resulting SPI/composite films were evaluated. A 15% addition of glycerol proved sufficient for good film formation. Among the biofibers, short SF microfibers were the most effective in enhancing breaking strength, while TEMPO-oxidized CNF (cellulose nanofiber) excelled among CNFs. Crosslinking with glyoxal significantly enhanced the mechanical properties, with the type of biofiber minimally affecting the mechanical properties of the crosslinked SPI composite films.
참고문헌 (27)
- Bae CH, "Fabrication of silk nanofibril-embedded regenerated silk fibroin composite fiber by wet spinning", Int J Indust Entomol, 45, pp.70~77 (2022)[DOI]
- Bai M, "A novel universal strategy for fabricating soybean protein adhesive with excellent adhesion and anti-mildew performances", Chem Eng J, 452, pp.139359~ (2023)[DOI]
- Choi HN, "Characteristics of Soybean Protein Resin Modified by Plasticizers and Cross-Linking Agents", J Adhes Interface, 12, pp.73~80 (2011)[DOI]
- Choi YY, "Dissolution, crystallilnity, and mechanical properties of silk sericin from Sericinjam silkworm cocoons", Int J Indust Entomol, 46, pp.9~15 (2023)[DOI]
- Denavi G, "Effects of drying conditions on some physical properties of soy protein films", J Food Eng, 90, pp.341~349 (2009)[DOI]
- González A, "Preparation and characterization of soy protein films reinforced with cellulose nanofibers obtained from soybean byproducts", Food Hydrocolloids, 89, pp.758~764 (2019)[DOI]
- Huang CF, "Study of various diameter and functionality of TEMPO-oxidized cellulose nanofibers on paraquat adsorptions", Polym Degrad Stabil, 161, pp.206~212 (2019)[DOI]
- Jensen A, "Development and characterization of soy protein films incorporated with cellulose fibers using a hot surface casting technique", LWT-Food Sci Technol, 60, pp.162~170 (2015)[DOI]
- Kim HJ, "Effects of various types of cellulose nanofibers on the physical properties of the CNF-based films", J Environ Chem Eng, 9, pp.106043~ (2021)[DOI]
- Kim HJ, "Effect of degumming ratio on wet spinning and post drawing performance of regenerated silk", Int J Biol Macromol, 67, pp.387~393 (2014)[DOI]
- Kim YE, "Effect of hot press time on the structure characteristics and mechanical properties of silk non-woven fabric", Int J Indust Entomol, 44, pp.12~20 (2022)[DOI]
- Kim YE, "Comparison of sericin produced through laboratory-and plant-scale extraction", Int J Indust Entomol, 47, pp.63~71 (2023)[DOI]
- Lee HG, "Morphology and crystallinity of silkworm cocoons with different rearing seasons", Int J Indust Entomol, 43, pp.16~21 (2021)[DOI]
- Lee HG, "Effect of wet treatment on the structure of various silkworm strain cocoons with different rearing seasons", Int J Indust Entomol, 44, pp.4~11 (2022)[DOI]
- Maquirriain MA, "Crude glycerine purification by solvent extraction", Braz J Chem Eng, 39, pp.235~249 (2022)[DOI]
- Martelli-Tosi M, "Soybean straw nanocellulose produced by enzymatic or acid treatment as a reinforcing filler in soy protein isolate films", Carbohydr Polym, 198, pp.61~68 (2018)[DOI]
- Peles Z, "Novel soy protein wound dressings with controlled antibiotic release : mechanical and physical properties", Acta Biomater, 8, pp.209~217 (2012)[DOI]
- Poyraz B, "Influence of PVA and silica on chemical, thermo-mechanical and electrical properties of Celluclast-treated nanofibrillated cellulose composites", Int J Biol Macromol, 104, pp.384~392 (2017)[DOI]
- Preece K, "Whole soybean protein extraction processes : A review", Innov Food Sci Emerg Technol, 43, pp.163~172 (2017)[DOI]
- Qin Z, "Preparation and characterization of soy protein isolate-based nanocomposite films with cellulose nanofibers and nano-silica via silane grafting", Polymers, 11, pp.1835~ (2019)[DOI]
- Rani S, "A review on material and antimicrobial properties of soy protein isolate film", J Polym Environ, 27, pp.1613~1628 (2019)[DOI]
- Um IC, "Structural characteristics and properties of the regenerated silk fibroin prepared from formic acid", Int J Biol Macromol, 29, pp.91~97 (2001)[DOI]
- Wang K, "Tough and strong soy protein film by integrating CNFs and MXene with photothermal conversion and UV-blocking performance", Cellulose, 29, pp.9235~9249 (2022)[DOI]
- Wang Z, "Biocompatible and antibacterial soy protein isolate", quaternized chitosan composite sponges for acute upper gastrointestinal hemostasis, 2021, pp.8, 1~12
- Wang Z, "Fabrication and characterization of cellulose nanofiber aerogels prepared via two different drying techniques", Polymers, 12, pp.2583~ (2020)[DOI]
- Wu Z, "Study on the soy protein-based adhesive cross-linked by glyoxal", J Renew Mater, 9, pp.205~ (2021)[DOI]
- Zhao Y, "Construction of highly biocompatible hydroxyethyl cellulose", soy protein isolate composite sponges for tissue engineering, 2018, pp.341, 402~413