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아세토페논 팽윤제를 이용한 폴리아미드-이미드 섬유의 캐치온 염색특성 연구

Study on the Cationic Dyeing Properties of Polyamide-imide Fiber using 2-Hydroxyacetophenone as a Swelling Agent

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초록

This study optimizes dyeing conditions for polyamide-imide fabric using cationic dyes. Dyeing and fastness characteristics of polyamide-imide fabric were investigated with three cationic dyes and 2-hydroxyacetophenone as a swelling agent under various dyeing conditions such as dye and swelling agent concentrations, dyeing temperature and time, pH of dye bath. The dyeing properties were evaluated in terms of dye exhaustion, K/S value and color fastness. The optimized dyeing temperature and time were 130℃ for 90 min for the dyes. Under weak acidic conditions in the range pH 5 to 7, the exhaustion of cationic dyes could be enhanced leading to higher adsorption. Wash and rubbing fastness properties were generally good, while light fastness was slightly low, which can be attributed to the poor photo-stability of the cationic dyes.

Abstract

This study optimizes dyeing conditions for polyamide-imide fabric using cationic dyes. Dyeing and fastness characteristics of polyamide-imide fabric were investigated with three cationic dyes and 2-hydroxyacetophenone as a swelling agent under various dyeing conditions such as dye and swelling agent concentrations, dyeing temperature and time, pH of dye bath. The dyeing properties were evaluated in terms of dye exhaustion, K/S value and color fastness. The optimized dyeing temperature and time were 130℃ for 90 min for the dyes. Under weak acidic conditions in the range pH 5 to 7, the exhaustion of cationic dyes could be enhanced leading to higher adsorption. Wash and rubbing fastness properties were generally good, while light fastness was slightly low, which can be attributed to the poor photo-stability of the cationic dyes.

참고문헌 (10)

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  2. A. Ray, "Syntheis of Polyamide-Imides Containing Ether and Sulfonamide Groups", Polymer J, 15, pp.169~ (1983)
  3. Cischem. Com Co., Ltd, "The World Latest Specialty Fibers Development and Market Status Report", pp.80~82 (2009), Cischem. Com Co., Ltd
  4. 김은미, "Swelling agent에 따른 메타계 아라미드 섬유의 Cationic dye 염색특성", 한국염색가공학회지, 24(1), pp.1~7 (2012), 한국염색가공학회
  5. I. S. Han, "Extreme Textiles; Specification and Application of Aramid Fiber", Fiber Technology and Industry, 10, pp.339~ (2006)
  6. E. A. Manyukov, "Study of Dyeing of Thermostable Para", meta-Aramid Fibre, 2005, pp.37(1), 54~
  7. E. C. Kim, "Super Fiber Material;Dyeability and Application of Aramid Fiber", Fiber Technology and Industry, 15(1), pp.34~ (2011)
  8. J. H. Park, "Effect of Swelling Agent on Dyeing of Aramid Fiber", Proceedings of the Korean Society of Dyers and Finishers Conference, 19(2), pp.145~146 (2007)
  9. 손영아, "Development of Cationic Dyeable Polyamide Substrates by Pretreatment with Synthetic Tanning Agent: Statistical Optimization and Analysis", 한국염색가공학회지, 21(5), pp.41~50 (2009), 한국염색가공학회
  10. 홍진표, "아라미드 소재의 침염 및 날염", 한국염색가공학회지, 23(4), pp.298~303 (2011), 한국염색가공학회

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