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Roll-to-roll 적용 가능한 마이크로 응집 구조를 갖는 EVA/SiO2 복합 필름의 산란 특성

The Scattering Property of EVA/SiO2 Composite Film Formed Micro-aggregation Structure for Roll-to-roll Process

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초록

We fabricated high transmission and high scattering poly(ethylene-co-vinyl acetate)(EVA) films embedding SiO2 nanoparticles to improve outcoupling efficiency in organic display. The 800nm diameter SiO2 nanoparticles aggregated and formed 1.56㎛ (with ±0.853㎛ standard deviation) diameter microparticles in EVA. The total transmission of scattering film was 83.3% on Polyethylene terephthalate(PET), which was higher than reference 82.8% PET substrate. The diffuse transmission and haze of the SiO2 embedded EVA film were 76.1% and 91.4%, respectively. The optimized condition was 1:1 weight ratio of SiO2 nanoparticles to EVA in Tetrahydrofuran(THF) solution. When the ratio of SiO2 was larger than 1, the total transmission decreased by the increase in backscattering of light due to high scattering. With the optimized condition, we could succeed to fabricate a large scale film(35m in length) with a roll-to-roll process.

Abstract

We fabricated high transmission and high scattering poly(ethylene-co-vinyl acetate)(EVA) films embedding SiO2 nanoparticles to improve outcoupling efficiency in organic display. The 800nm diameter SiO2 nanoparticles aggregated and formed 1.56㎛ (with ±0.853㎛ standard deviation) diameter microparticles in EVA. The total transmission of scattering film was 83.3% on Polyethylene terephthalate(PET), which was higher than reference 82.8% PET substrate. The diffuse transmission and haze of the SiO2 embedded EVA film were 76.1% and 91.4%, respectively. The optimized condition was 1:1 weight ratio of SiO2 nanoparticles to EVA in Tetrahydrofuran(THF) solution. When the ratio of SiO2 was larger than 1, the total transmission decreased by the increase in backscattering of light due to high scattering. With the optimized condition, we could succeed to fabricate a large scale film(35m in length) with a roll-to-roll process.

참고문헌 (18)

  1. T. Yamasaki, "Organic Light-Emitting Device with an Ordered Monolayer of Silica Microspheres as a Scattering Medium", Applied Physics Letters, 76(10), pp.1243~ (2000)
  2. J. J. Shiang, "Experimental Demonstration ofIncreased Organic Light Emitting Device Output via Volumetric Light Scattering", J. of Applied Physics, 95(5), pp.2889~ (2004)
  3. M. K. Wei, "Method to Evaluate the Enhancement of Luminance Efficiency in Planar Oled Light Emitting Devicesfor Microlens Array", Optics Express, 12(23), pp.5777~ (2004)
  4. J. Lim, "Enhanced Out-coupling Factor of Microcavity Organic Light-Emitting Devices with Irregular Microlens Array", Optics Express, 14(14), pp.6564~ (2006)
  5. F. Li, "Enhanced Light Extraction from Organic Light-Emitting Devices by Using Microcontact Printed Silica Colloidal Crystals", Organic Electronics, 8(5), pp.635~ (2007)
  6. N. Nakamura, "Light Extraction Analysis of Organic Light Emitting Diodes Fabricated on High Refractive Index Glass Scattering Layer", J. of Applied Physics, 117(5), pp.055502~ (2015)
  7. K. H. Kim, "Enhancing Light-extraction Efficiency of Oleds with High-and Low-refractive-index Organic-inorganic Hybrid Materials", Organic Electronics, 36, pp.103~ (2016)
  8. T. Nakamura, "Enhanced Coupling of Lightfrom Organic Electroluminescent Device Using Diffusive Particle Dispersed High Refractive Index Resin Substrate", Optical Review, 13(2), pp.104~ (2006)
  9. R. Bathelt, "Light Extraction from Oleds for Lighting Applications through Light Scattering", Organic Electronics, 8(4), pp.293~ (2007)
  10. J. Lee, "Enhancement of Light-extraction Efficiency of Organic Light-emitting Diodes Using Silica Nanoparticles Embedded in TiO2 Matrices", Optics Express, 22(103), pp.A705~ (2014)
  11. M. Harada, "Characterization of Light Extraction Efficiency for Woleds with Light-out-coupling Layer", J. of the Society for Information Display, 23(1), pp.1~ (2015)
  12. J. Hegmann, "SiO2-TiOv Scattering Layers Prepared by Sol-Gel Processing for Light Management in Thin Film Solar Cells", J. of Sol-Gel Science and Technology, 74(3), pp.585~ (2015)
  13. T. W. Koh, "Enhanced Outcoupling in Organic Light-emitting Diodes Via a High-index Contrast Scattering Layer", Acs Photonics, 2(9), pp.1366~ (2015)
  14. S. Luo, "Light-scattering Capacity of Ethylene-vinyl Acetate Copolymers in Polypropylene: Toward High Haze and Transmittance", J. of Applied Polymer Science, 133(34), pp.42844~ (2016)
  15. W. Suthabanditpong, "Facile Fabrication of Light Diffuser Films Based on Hollow Silica Nanoparticles as Fillers", Advanced Powder Technology, 27(2), pp.454~ (2016)
  16. W. Stark, "Investigation of Ethylene", vinyl Acetate Copolymer(EVA) by Thermal Analysis DSC and DMA, 2011, pp.30(2), 236~
  17. S. Takahashi, "Optical Properties of Polymer Blends Composed of Poly(Methyl Methacrylate) and Ethylene-vinyl Acetate Copolymer", European Polymer J., 48(5), pp.974~ (2012)
  18. J. G. Lim, "Computation of Refractive Index and Optical Retardation in Stretched Polymer Films", Optics Express, 25(14), pp.16409~ (2017)

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