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Sensitivity Enhancement in Solution NMR via Photochemically Induced Dynamic Nuclear Polarization

이정호|임종혁
한국자기공명학회 (Korean Magnetic Resonance Society)|2017.03|Journal of the Korean Magnetic Resonance Society|제21권 제1호|pp. 1-6

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참고문헌

키워드

Photo-CIDNPSolution NMR SensitivityRadical Pair MechanismSolid-state Photo-CIDNP
주제분류화학

초록

Enhancements in NMR sensitivity have been the main driving force to extend the boundaries of NMR applications. Recently, techniques to shift the thermally populated nuclear spin states are employed to gain high NMR signals. Here, we introduce a technique called photochemically induced dynamic nuclear polarization (photo-CIDNP) and discuss its progresses in enhancing the solution-state NMR sensitivity.

Abstract

Enhancements in NMR sensitivity have been the main driving force to extend the boundaries of NMR applications. Recently, techniques to shift the thermally populated nuclear spin states are employed to gain high NMR signals. Here, we introduce a technique called photochemically induced dynamic nuclear polarization (photo-CIDNP) and discuss its progresses in enhancing the solution-state NMR sensitivity.

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