악취 Sampling Bag의 황 화합물질 안정성 연구
A Study on Stability Evaluation of Sulfur Compounds in Sampling Bag
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초록
In this study, stability of 4 sulfur compounds (H2S, CH3SH, DMS, and DMDS) was investigated for up to 96 h (at 6, 12, 24, 48, 72, and 96 h time points). For these experiments, each sulfur standard was prepared at 10 nmol/mol in a 10 L sampling bag (Teldlar bag). To investigate the stability of the sulfur compounds, regression analysis was applied to the data obtained by the concentration reduction over time at the 95% confidence level. According to regression analysis, the concentration of sulfur compounds in 48 h had statistically significant difference (P-value < 0.05) from stability of 4 sulfur compounds (H2S, CH3SH, DMS, and DMDS). The results also indicated that the heavy sulfur compounds (DMS and DMDS) tend to show more rapid concentration reduction than lighter sulfur compounds (H2S and CH3SH). This study can be used to improve the reliability of analysis by judging quantitative concentrations of sulfur compounds when controlling odor-polluted areas.
Abstract
In this study, stability of 4 sulfur compounds (H2S, CH3SH, DMS, and DMDS) was investigated for up to 96 h (at 6, 12, 24, 48, 72, and 96 h time points). For these experiments, each sulfur standard was prepared at 10 nmol/mol in a 10 L sampling bag (Teldlar bag). To investigate the stability of the sulfur compounds, regression analysis was applied to the data obtained by the concentration reduction over time at the 95% confidence level. According to regression analysis, the concentration of sulfur compounds in 48 h had statistically significant difference (P-value < 0.05) from stability of 4 sulfur compounds (H2S, CH3SH, DMS, and DMDS). The results also indicated that the heavy sulfur compounds (DMS and DMDS) tend to show more rapid concentration reduction than lighter sulfur compounds (H2S and CH3SH). This study can be used to improve the reliability of analysis by judging quantitative concentrations of sulfur compounds when controlling odor-polluted areas.
참고문헌 (23)
- Y. Nagata, "Odor intensity and door threshold value", Journal of Japan Air Cleaning Association, 41, pp.17~25 (2003)
- K. H. Kim, "A method to test the detectability of GC", PFPD for an extended concentration range with respect to reduced sulfur compounds, 2008, pp.31, 1761~1768
- 양성봉, "악취의 성분분석" (1997), 동화기술
- 양성봉, "우리 나라의 악취 규제제도", 실내환경 및 냄새 학회지, 1(1), pp.6~15 (2002), 한국냄새환경학회
- 악취물질 발생원 관리방안 개선을 위한 조사연구, "환경부", 267~287 (2001)
- "법제처"[URL]
- 환경부, "악취방지법, 별표 3, 배출허용기준 및 엄격한배출허용기준의 설정범위", ~ (2014)
- W. Wardencki, "Problems with the determination of environmental sulphur compounds by gas chromatography", Journal of Chromatography A, 793, pp.1~19 (1998)
- Y. Inomata, "Simultaneous measurement of volatile sulfur compounds using ascorbic acid for oxidant removal and gas chromatography–flame photometric detection", Journal of Chromatography A, 864, pp.111~119 (1999)
- B. M. Davison, "A method for sampling dimethyl sulfide in polluted and remote marine atmospheres", Atmospheric Environment, 28, pp.1721~1729 (1994)
- 김기현, "테들러 백을 이용한 대기 중 황성분의 채취: 보정인자의 적용을 위한 예비연구", 한국지구과학회지, 25(4), pp.265~269 (2004), 한국지구과학회
- 환경부, "악취공정시험기준", ~ (2014)
- "ISO Guide 34, General requirements for the competence of reference material producers", ~ (2016)
- "ISO Guide 30, Terms and definitions used in connection with reference materials", ~ (2015)
- "ISO Guide 35, Reference materials-general and statistical principles for certification", ~ (2006)
- 손윤석, "시료채취 용기에 따른 황계열 악취물질의 안정도 평가", 한국환경분석학회지, 10(2), pp.66~71 (2007), 한국환경분석학회
- 전선주, "캐니스터와 Tedlar-bag 시료채집법을이용한 대기 중의 휘발성유기황화합물의 측정", 한국대기환경학회지, 15, pp.417~428 (1999)
- W. C. Kuster, "Quantification of the losses of gaseous sulfur compounds to enclosure walls", Environmental Science & Technology, 21, pp.810~815 (1987)
- S. J. Jeon, "Measurment of volatile organic sulfur compounds in ambient air by canister and tedlar bag sampling method", Journal of Korean Society for Atmospheric Environment, 15, pp.417~428 (1999)
- A. T. Nielsen, "Quantification of volatile sulfur compounds in complex gaseous matrices by solid-phase microextraction", Journal of Chromatography A, 963, pp.57~64 (2002)
- 조효재, "Tedlar-bag 시료채집법을 이용한 황화합물의 경시적 농도 변화특성 : 시료의 생성방식의 차이에 따른 비교연구", 분석과학, 24(3), pp.212~218 (2011), 한국분석과학회
- 오민환, "Stability evaluation of sulfur compounds in tedlar bag", 한국냄새환경학회 추계학술대회 발표논문집, pp.18~21 (2011)
- 조영덕, "Comparison of sulfur gaseous stabilities in sampling bags", 한국냄새환경학회 추계학술대회 발표논문집, pp.74~75 (2012)
