낙동강수계 유기물 분포특성과 소독부산물 생성능과의상관성에 관한 연구
Correlation between Dissolved Organic-Carbon Distribution Characteristics and Disinfection Byproduct Formation Potential in the Nakdong River
1
조회
0
다운로드
3
인용
0
참고문헌
키워드
초록
Recently, there have been steady increases in the concentration of disinfection byproducts (DBP) in water treatment plants using the Nakdong River as a source. Therefore, a study was carried out investigating the correlation between organic matter and DBP in the Nakdong River water system. There were no significant differences in organic matter concentrations between the main stream and tributaries of the Nakdong River during this study. However, in July and August, the months of heaviest rainfall, humic substances (HS), known to be DBP precursors, increased by over 60% compared with May and June. The origin of organic matter in the Nakdong River was analyzed using an HS-diagram, which generally showed pedogenic fulvic acid (FA) characteristics; this is hypothesized to be the effect of organic material entering with turbid water from upstream. While there was a 26% increase in organic matter in July and August, the DBP trihalomethanes formation potential (THMFP) and haloacetic acid formation potential (HAAFP) increased by 36% and 91%, respectively. Thus, DBP increased at a higher than organic matter during this study. The DBP formation potential per unit organic matter was found to be 0.103 for THMFP and 0.016 for HAAFP.
Abstract
Recently, there have been steady increases in the concentration of disinfection byproducts (DBP) in water treatment plants using the Nakdong River as a source. Therefore, a study was carried out investigating the correlation between organic matter and DBP in the Nakdong River water system. There were no significant differences in organic matter concentrations between the main stream and tributaries of the Nakdong River during this study. However, in July and August, the months of heaviest rainfall, humic substances (HS), known to be DBP precursors, increased by over 60% compared with May and June. The origin of organic matter in the Nakdong River was analyzed using an HS-diagram, which generally showed pedogenic fulvic acid (FA) characteristics; this is hypothesized to be the effect of organic material entering with turbid water from upstream. While there was a 26% increase in organic matter in July and August, the DBP trihalomethanes formation potential (THMFP) and haloacetic acid formation potential (HAAFP) increased by 36% and 91%, respectively. Thus, DBP increased at a higher than organic matter during this study. The DBP formation potential per unit organic matter was found to be 0.103 for THMFP and 0.016 for HAAFP.
참고문헌 (16)
- Y. J. Jung, "NOM characteristics by the turbidity in-flow in lake Soyang", Proceedings of Korean Society of water & wastewater and Korean Society on water Environment, Autumn Symposium, pp.55~ (2007)
- P. Westerhoff, "Seasonal occurrence and degradation of 2-methylisoborneol in water supply reservoirs", Water Research, 39, pp.4899~4912 (2005)[DOI]
- Ministry of Environment(MOE), "Water Quality Standard Guide Book", pp.70~ (2017)
- 유순주, "금강 수계에서 소독부산물 생성에 미치는 유기물 특성", 한국물환경학회지, 19(6), pp.707~714 (2003), 한국물환경학회
- 손희종, "상수원수중에 함유된 천연유기물질 분자량 크기가 염소 소독부산물 생성에 미치는 영향", 대한환경공학회지, 26(11), pp.1278~1290 (2004), 대한환경공학회
- J. Kim, "Chlorination by-products in surface water treatment process", Desalination, 151, pp.1~9 (2002)
- G. L. Amy, "Occurrence of disinfection by-products precursor in source water and DBPs in finished waters", Proceedings of the fourth International Workshop on Drinking Water Quality Management and Treatment Technology, pp.59~70 (1986)
- C. Y Chang, "The organic precursors affecting the formation of disinfection by-products with chlorine dioxide", Chemosphere, 44, pp.1153~1158 (2001)[DOI]
- 최일환, "기존수처리 공정 및 고도정수처리 공정에서 NOM의 분자크기 분포 변화", 한국물환경학회지, 24(6), pp.682~689 (2008), 한국물환경학회
- S. A. Huber, "Characterization of aquatic humic and non-humic matter with size-exclusion chromatography-organic carbon detection-organic nitrogen detection (LC-OCD-OND)", Water Research, 45, pp.879~885 (2011)[DOI]
- I. H. Choi, "Application of LC-OCD method for the characterization of NOM in Geum River", Proceedings of Korean Society of water & wastewater and Korean Society on water Environment, Autumn Symposium, pp.P~81 (2016)
- 염철민, "유기물 발생원에 따른 소독부산물 생성능", 한국물환경학회지, 19(1), pp.127~133 (2003), 한국물환경학회
- T. Dittmar, "Recalcitrant dissolved organic matter in the ocean: Major contribution of small amphiphilics", Marine Chemistry, 82, pp.115~123 (2003)[DOI]
