지오폴리머의 침지 후 물성변화
Property change of geopolymers after immersion
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초록
본 연구는 오토클레이브 양생시편이 예상과 달리 초기강도는 잘 발현되지 않는 반면, 수중에 장기 침지할 경우 압축강도가 향상되는 현상을 규명하기 위해 시작되었다. 증류수 및 알칼리 용액에 침지하였고, 세 가지 양생방법이 시도되었다. 알칼리용액에 침지할 경우 증류수 침지 시편이 추가적인 지오폴리머 반응에 의해 보다 더 높은 압축강도를 가질 것으로 예상하였으나, 실제로 추가적인 지오폴리머 반응에 의해 생성된 결정립들과 알칼리골재 반응에 의한 시편의 팽창 때문에 21일 침지 후 침지용액에 의한 압축강도의 변화는 크게 나타나지 않은 것으로 사료되었다. 지오폴리머의 수중 및 알칼리용액 내 장기공용성을 확보하기 위해서는 오토클레이브를 이용하여 양생 후 21일 이상 수중 침지를 시키면서 숙성(aging) 시키는 것이 바람직 한 것으로 결론지을 수 있었다.
Abstract
This study was started to investigate why autoclave curing (AC) specimen showed an improvement in compressive strength after immersion in water for a long time, although AC specimen did not showed a high initial compressive strengthunlike our expectations. Distilled water and alkaline solutions were used for immersion and three different curing methods were engaged. It was expected that the compressive strength would be improved after immersion in alkaline solutions;however, there was little difference in compressive strength after 21 day immersion because both new crystallites produced by additional geopolymerization and expansion caused by the alkaline aggregate reaction may prevent the additionalimprovement in compressive strength. It was concluded that in order to secure the long-term commonality and underwater stability of the geopolymers, it is desirable aging geopolymers while immersing it underwater for more than 21 days after curing using an autoclave.
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