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Effect of accelerational perturvations on physical vapor transport crystal growth under microgravity environments

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주제분류재료공학

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Abstract

For PB = 50, DT = 10 K, Ar = 5, Pr = 2.36, Le = 0.015, Pe = 1.26, Cv = 1.11, the intensity of solutal convection (solutal Grashof number Grs = 3.44 ?104) is greater than that of thermal convection (thermal Grashof number Grt = 1.81 ?103) by one order of magnitude, which is based on the solutally buoyancy-driven convection due to the disparity in the molecular weights of the component A (Hg2Cl2) and B (He). With increasing the partial pressure of component B from 10 up to 200 Torr, the rate is decreased exponentially. The convective transport decreases with lower g level and is changed to the diffusive mode at 0.1 g0. In other words, for regions in which the g level is 0.1 g0 or less, the diffusion-driven convection results in a parabolic velocity profile and a recirculating cell is not likely to occur. Therefore a gravitational acceleration level of less than 0.1 g0 can be adequate to ensure purely diffusive transport.

참고문헌 (9)

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  3. Mayer, "The mercury-mercuricEffect of accelerational perturbations on physical vapor transport crystal growth under microgravity environments 209chloride system" (1960)
  4. Markham, "Numerical modeling of difusive-convective physicalvapor transport in cylindrical vertical ampoules" (1981)
  5. Duval, "Convection in the physical vapor trans-port proces-- I" (1994)
  6. A, "Efectsof buoyancy-driven flow and thermal boundary condi-tions on physical vapor transport" (1992)
  7. H. Zhou, "Physical vapor transport of zinc-telluride by disocia-tive sublimation", 167 (1996)
  8. F. Rosenberger, "Physical vapor transport revised", 171 (1997)
  9. Singh, "Evalua-tion of transport conditions during PVT" (1989)

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