비스무스와 지르코늄 첨가를 통한 세리아계 친환경 노란색 안료 특성에 관한 연구
Effect of Bi and Zr addition on yellow colour properties of environmentfriendly ceria-based pigments
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초록
무기안료는 우수한 열적, 화학적 안정성으로 인해 페인트, 고화도 세라믹 잉크, 아트 타일, 건물의 외장재 등의 다양한 응용 분야에 적용될 수 있어 큰 관심을 받고 있다. 기존에는 PbCrO4, CdS, CdSe 등의 조성이 노란색 무기 안료로 널리 사용되어 왔으나 Cd, Cr, Pb, Se 같은 유해물질을 포함하고 있어 최근에는 사용에 제한되고 있다. 따라서 본 연구에서는 ceria 기반의 조성을 이용하여 고상법으로 친환경 노란색 무기안료를 합성하였다. XRD와 SEM을 통해 합성된 Ce1 − xZrxBiyO2 − y/2 노란색 무기안료의 결정구조와 형상을 확인하였고, UV-vis. spectrophotometer와 CIE L*a*b* 분석으로 Zr과 Bi함량에 따른노란색 무기안료의 발색 특성 변화를 확인하였다. 노란색 무기안료의 결정구조는 주로 하소온도의 변화에 의존하는 것으로확인되었고, 발색 특성과 흡수단은 하소온도와 Zr, Bi 함량이 모두 영향을 미치는 것으로 나타났다. 결과적으로 합성된 모든 무기안료는 자외선과 500 nm 이하의 가시광선을 효율적으로 흡수하였고, Ce0.44Zr0.36Bi0.20O0.19(x = 0.36, y = 0.20) 조성의무기안료에서 가장 선명한 노란색 색조를 확인할 수 있었다.
Abstract
Inorganic pigments have been received a great attention for various applications including paint, glazed ceramic ink, art tile, and building exterior due to their excellent thermal and chemical stability. Traditionally, the compositions of PbCrO4, CdS and CdSe have been widely used as a yellow inorganic pigment. However, the use of these compositions has been restricted in recent years, because they contain harmful elements such as Cd, Cr, Pb and Se. In this study, new environment-friendly ceria-based pigment was synthesized using solid state reaction. Crystal structure and morphology of the obtained Ce1 − xZrxBiyO2 − y/2 yellow pigment were analyzed using XRD and SEM, respectively. Substitutional effect of Zr and Bi on the pigment color was analyzed using UV-vis. spectrophotometer and CIE L*a*b* analysis. The crystal structure of the obtained pigments was dependent on the calcination temperature. The color characteristics and absorption band of the pigments were dependent on the calcination temperature and Zr, Bi contents. As a result, all the obtained yellow pigments showed the effective absorption ranged from ultraviolet to visible light, and Ce0.44Zr0.36Bi0.20O0.19 (x = 0.36, y = 0.20) pigment showed the most brilliant yellow color.
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